Assertion (A) : At high pressure, the compressibility factor Z is (1+pbRT)Reason (R : At high pressure van der Waals' equation is modified as p(V - b) = RT

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Both A and R are correct; R is the correct explanation of A.

Both A and R are correct; R is not the correct explanation of A.

A is correct; R is incorrect.

Both A and R are incorrect.

answer is A.

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Detailed Solution

van der Waals' equation isp+aV2(V-b)=RTAt high pressure, p(V-b)=R Tp V-p b=R TpVRT=1+pbRTpVRT=Z, then Z=1+pbRT

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