Assertion (A) : At high pressure, the compressibility factor Z is (1+pbRT)Reason (R : At high pressure van der Waals' equation is modified as p(V - b) = RT
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a
Both A and R are correct; R is the correct explanation of A.
b
Both A and R are correct; R is not the correct explanation of A.
c
A is correct; R is incorrect.
d
Both A and R are incorrect.
answer is A.
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Detailed Solution
van der Waals' equation isp+aV2(V-b)=RTAt high pressure, p(V-b)=R Tp V-p b=R TpVRT=1+pbRTpVRT=Z, then Z=1+pbRT