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Q.

Assume for CH33C−,CH32CH−,CH3−CH2− and CH3− groups the order of inductive effect and hyper conjugation effect is

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a

30−>20−>10−>CH3−and  30−<20−<10−

b

30−<20−<10−20−>10−>CH3−groups

c

For both effects  30−>20−>10−>CH3 groups

d

None of the above

answer is A.

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Detailed Solution

For inductive effect, more the number of alkyl groups more is inductive effect for hyper conjugation effect, but for hyperconjugation greater the number of α - Hydrogen higher will be hyper conjugation effect. Since in hyperconjugation Hydrogen atoms involve.
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Assume for CH33C−,CH32CH−,CH3−CH2− and CH3− groups the order of inductive effect and hyper conjugation effect is