Q.

Assumei)  FeH2O5NO+2  obeys EAN  rule,ii)  the oxidation state of central metal 'Fe' is +2, Find out  the oxidation state of NO in the given complex  ?

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a

Zero

b

1

c

2

d

-1

answer is A.

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Detailed Solution

FeH2O5NO+2 +2(1)+50+1x=+2; 2+x=+2; x=0;therefore oxidation state of NO in the above complex is zeroEAN = Z-Oxidation state +2(coordination number)EAN = 26-2+6(2)=36
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