Assuming that water vapour is an ideal gas, the internal energy change ∆U when 1 mole of water is vaporised at 1 bar pressure and 1000C, (given: molar enthalpy of vaporisation of water = 41 kJ mol-1 at 1 bar and 373 K and R = 8.3 J mol-1 K mol-1) will be
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