The azeotropic mixture of water (8.P.= 100oC) and HCI (B.P : 86oC) boils at about 120oC. During fractional distillation of this mixture it is possible to obtain :

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pure HCI

Pure H2O

pure H2O as well as pure HCI

neither H2O nor HCI

answer is D.

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Detailed Solution

From an azeotropic mixture the components cannot be separated at boiling point because it is a constant temperature boiling mixture.

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