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Q.

An azeotropic mixture of water(b.pt=1000c) and HCl (b.pt = 850C) boils at 108.50c. When this mixture is distilled, it is possible to obtain

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a

Pure HCl

b

Pure water

c

Both HCl & water

d

Neither HCl nor H2O in pure state

answer is D.

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Detailed Solution

BP of H2O = 100ocBP of HCl = 85ocBP of (HCl+H2O) azeotrope = 108.5ocIt is a maximum boiling azeotropeIt is not possible to separate the components of an azeotropeBecause both the components boil at same temperatureAn azeotrope is a constant boiling mix. neither HCl nor H2O can be obtained in pure state by fractional distillation
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