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Q.

a and b are Vander Waals constants for gases. Chlorine is more easily liquefied than ethane because ___?

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a

"  a " and " b " for Cl2>C2H6

b

" a" and " b'' for C2H6>Cl2

c

"  a " for Cl2< "  a " for C2H6 but"  b " for Cl2> "  b "   for C2H6

d

"a" for Cl2 > "  a " for C2H6 but " b " for Cl2<"b " for C2H6

answer is D.

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Detailed Solution

a                                      b Cl2     6.49L2 bar mol -2         0.05622 lit.mol -1C2H6  5.49 L2 bar mol-2         0.06380 lit.mol -1“a” is proportional to the intermolecular forces present while “b” represents molecular size.
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