a and b are Vander Waals constants for gases. Chlorine is more easily liquefied than ethane because ___?
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a
" a " and " b " for Cl2>C2H6
b
" a" and " b'' for C2H6>Cl2
c
" a " for Cl2< " a " for C2H6 but" b " for Cl2> " b " for C2H6
d
"a" for Cl2 > " a " for C2H6 but " b " for Cl2<"b " for C2H6
answer is D.
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Detailed Solution
a b Cl2 6.49L2 bar mol -2 0.05622 lit.mol -1C2H6 5.49 L2 bar mol-2 0.06380 lit.mol -1“a” is proportional to the intermolecular forces present while “b” represents molecular size.