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Q.

In the balanced chemical reaction,IO3−+aI−+bH+⟶cH2O+dI2a, b, c, and d respectively correspond to

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a

5,6,5,5

b

5,3,6,3

c

3,5,3,6

d

5,6,3,3

answer is D.

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Detailed Solution

IO3−+aI−+bH+→cH2O+dI2 Step 1:I−1→I2 (oxidation) IO3−→I2 (reduction) Step 2:2IO3−+12H+→I2+6H2O Step 3:2IO3−+12H++10e→I2+6H2O2I−→I2+2e Step 4:2IO3−+12H++10e−→I2+6H2O2I−→I2+2e5 Step 5:2IO3−+10I−+12H+→6I2+6H2OIO3−+5I−+6H+→3I2+3H2O On comparing, a=5,b=6,c=3,d=3

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