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a
For H2 at 0ºC, molecular attractive forces are weak and size effect dominates its behavior resulting that (Z>1)
b
For N2 at 0ºC, attractive forces are large enough to cause negative deviation upto 150 atm thus (Z<1) after which size effect dominates thus (Z>1)
c
For CO2, intermolecular attraction is large even at 40ºC resulting (Z<1) even at high pressures
d
For CO2 and N2¸two effects compensate each other at a particular pressure where, Z=1
answer is A.
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