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Q.

Based on the given diagram, which of the following statements regarding the homogenous solutions of two volatile liquids are correct? (1) Plots 4D and BC show that Raoult's law is obeyed for the solution in which B is a solvent and A is the solute and as well as for that in which A is solvent and B is solute.(2) Plot CD shows that Dalton's law of partial pressures is obeyed by the binary solution of components A and B.(3) EF + EG = EH; and AC and BD correspond to the vapour pressures of the pure solvents A and B respectively. Select the correct answer using the options given below:

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a

Only 1

b

2 and 3

c

1 and 3

d

All

answer is D.

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Detailed Solution

Plots AD show vapour pressure of B.Plots BC show vapour pressure of A.Plot CD show vapour pressure of liquid solution containing A and B. Volatile components.P=PA+PB∴ EH=EF+EG

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Based on the given diagram, which of the following statements regarding the homogenous solutions of two volatile liquids are correct? (1) Plots 4D and BC show that Raoult's law is obeyed for the solution in which B is a solvent and A is the solute and as well as for that in which A is solvent and B is solute.(2) Plot CD shows that Dalton's law of partial pressures is obeyed by the binary solution of components A and B.(3) EF + EG = EH; and AC and BD correspond to the vapour pressures of the pure solvents A and B respectively. Select the correct answer using the options given below: