Q.
Basic character of amines in non-gaseous phase or in polar solvent is explained on the basis of which factor(s)
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a
Inductive effect only
b
Solvation effect along with inductive effect
c
Inductive effect, solvation effect and steric hindrance
d
Cannot be predicted
answer is C.
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Detailed Solution
The basic strength of amines in polar solvent (or) non-gaseous phase will be explained by summation of three factors 1) Inductive effect (Acc to this the order of basicity is -amine > -amine > -amine> NH3)2) Solvation effect α1size of the amineRNH2>R2NH>R3N3) According to Steric hindrance the order of basicity of amines is 20>10>30
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