Q.
The basic character of hydrides of the V-group elements decreases in the order
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a
SbH3>PH3>AsH3>NH3
b
NH3>SbH3>PH3>AsH3
c
NH3>PH3>AsH3>SbH3
d
SbH3>AsH3>PH3>NH3
answer is C.
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Detailed Solution
NH3>PH3>AsH3>SbH3On moving down the group atomic size increases and availability of lone pair decreases. Hence, basic character decreases.
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