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The BCl3 is a planar molecule, whereas NCl3 is pyramidal because

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a
N-Cl bond is more covalent than B-CI bond
b
B-CI bond is more polar than N-Cl bond
c
nitrogen atom is smaller than boron
d
BCl3 has no lone pair but NCl3 has a lone pair of electron

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detailed solution

Correct option is D

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