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By Expert Faculty of Sri Chaitanya
Question

A black coloured compound (A) on reaction with dil. H2SO4 gives a gas (B) and almost a colourless solution from which a pale green compound crystallizes out. Gas (B) on passing through a solution of an acid (C) gives a white turbidity (D). Gas (B) when passed through an acidified solution of a compound (E) gives a precipitate (F) soluble in dilute HNO3. After boiling this solution, addition of an excess of NH4OH results in an intense blue coloured compound (G). A chocolate brown precipitate (H) is obtained when acetic acid and aqueous K4[Fe(CN)6] is added to the solution containing (G). On addition of an aqueous solution of BaCl2 to an aqueous solution of (E) a white precipitate insoluble in dilute HCl is obtained. 

Moderate
Question

Compounds A, D and F respectively are

Solution

A - FeS                         B - H2S
C - HNO3                      D - S 
E - CuSO4                     F - CuS
G - [Cu(NH3)4](NO3)2   H - Cu2Fe(CN)6
 

Question

Compounds G and H respectively are

 

Solution

A - FeS                         B - H2S
C - HNO3                      D - S 
E - CuSO4                     F - CuS
G - [Cu(NH3)4](NO3)2   H - Cu2Fe(CN)6
 


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