The boiling point of 0.2 mol kg–1 solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is true in the case ?
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a
Molecular mass of X is less than the molecular mass of Y.
b
Y is undergoing dissociation in water while X undergoes no change
c
X is undergoing dissociation in water
d
Molecular mass of X is greater than the molecular mass of Y
answer is C.
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Detailed Solution
BP of 0.2m 'X' (aq.) > BP of 0.2m 'Y' (aq.)This indicates elevation in BP in aq. sol. of 'X' is greater than in aq. sol. of 'Y'This is possible when(a) 'X' dissociates in water & 'Y' neither dissociates nor associates in water(b) 'X' neither dissociates nor associates in water & 'Y' associates in water