Q.
The bond length of HCl molecule is 1.275 Ao and its dipole moment is 1.03 D. The ionic character of the molecule (in per cent) ( charge of the electron=4.8×10-10 esu) is
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a
100
b
67.3
c
33.66
d
16.83
answer is D.
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Detailed Solution
Given,observed dipole moment = 1.03 DBond length of HCl molecule, d = 1.275 Ao = 1.275 ×10-8 cm Charge of electron, e-=4.8×10-10 esuPercentage ionic character = ?Theoretical value of dipole moment = e×d =4.8×10-10×1.275×10-8 esu.cm =6.12×10-18 esu.cm = 6.12 DPercentage ionic character
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