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Q.

By assuming enthalpy change of a reversible reaction is temperature independent, the incorrect relation between equilibrium constants at different temperature for given enthalpy change is ____

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a

When ΔH=+ve;K2>K1 if T2>T1

b

When ΔH=-ve;K1>K2 if T2>T1

c

When ΔH=-ve;K2>K1 if T2>T1

d

When ΔH=+ve;K1>K2 if T1>T2

answer is C.

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Detailed Solution

According to Vant Hoff equationlnK2K1=∆HR(1T1-1T2)For exothermic reaction  Keqα1TFor endothermic reaction KeqαT
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