By assuming enthalpy change of a reversible reaction is temperature independent, the incorrect relation between equilibrium constants at different temperature for given enthalpy change is ____
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a
When ΔH=+ve;K2>K1 if T2>T1
b
When ΔH=-ve;K1>K2 if T2>T1
c
When ΔH=-ve;K2>K1 if T2>T1
d
When ΔH=+ve;K1>K2 if T1>T2
answer is C.
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Detailed Solution
According to Vant Hoff equationlnK2K1=∆HR(1T1-1T2)For exothermic reaction Keqα1TFor endothermic reaction KeqαT