Q.
By SN1 reaction allyl chloride changes to allyl alcohol as shownCH2=CH−CH2Cl+H2O⟶SN1CH2=CHCH2OH I II Select the correct product II(C1414- an isotope of carbon)
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a
CH2=CHCH142OH
b
CH142=CHCH2OH
c
Both (1) and (2) are correct
d
None of these is correct
answer is C.
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Detailed Solution
SN1 means unimolecular (1) nucleophilic (N) substitution (S). Rate is independent of molar concentration of H2O but is dependent on molar concentration of CH2=CHCH2−Cl.CH2=CH−CH142CI⇌CH2=CH CH2⊕ 14 Carbon cation (Intermediate)Carbocation exists as resonance structures. Thus H2O (nucleophile) can attack at C⊕CH2=CH⊕−CH214 +H2O→CH142=CH−CH142OH 14C at original position) CH2⊕−CH=CH214+H2O→CH2=CH−CH2OH(14C) at changed position due to resonance).
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