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Fundamentals of thermodynamics

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By Expert Faculty of Sri Chaitanya
Question

At 25°C, 50 g of iron reacts with HCI to form FeCl2 The evolved hydrogen gas expands against a constant pressure of 1 bar. The work done by the gas during this expansion is   J. (Round off to the Nearest Integer)

[Given R=8.314dmol1K1 Assume, hydrogen is an ideal gas: [Atomic mass off Fe is 55.85 u]

Moderate
Solution

T=298K,R=8.314JmolK

 Chemical reaction is

Fe+2HClFeCl2+H2(g)50g P=1bar=5055.85mol

 Work done for 1 mol gas

=Pext×ΔV=ΔngRT=1×8.314×298J

 Work done for 5055.85mol of gas

=8.314×298×5055.85J=2218.059J=2218J


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