First slide

Chemical Properties of Alcohols

Question

$C_{4} H_{10} O (A) \overset{K M n O_{4} / H^{+}}{\to} C_{4} H_{8} O_{2} .$ $‘ A ’ w h e n t r e a t e d w i t h P C l_{3} f o l l o w e d b y r e d u c t i o n w i t h$ $Z n / H C l g i v e s n - b u \tan e . ‘ A ’ i s$

Moderate

A

$n - b u t y l a l c o h o l$
B

$2^{0} b u t y l a l c o h o l$
C

$I s o b u t y l a l c o h o l$
D

$3^{0} b u t y l a l c o h o l$

Solution

$O n S t r o n g O x i d a t i o n$
$A l l c o m p o u n d s c o n t a i n s a m e n u m b e r o f c a r b o n a t o m s$
$∴ ‘ A ’ c a n b e (1) (o r) (3)$
$I f A i s o p t i o n (3)$
$S o ‘ A ’ c a n n o t b e (3)$
$C H_{3} C H_{2} C H_{2} C H_{2} O H \overset{P C l_{3}}{\to} C H_{3} C H_{2} C H_{2} C H_{2} C l \to_{}^{Z n / H C l} \underset{n - b u \tan e}{C H_{3} C H_{2} C H_{2} C H_{3}}$

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