At 1000C the vapour pressure of a solution of 6.5g of a solute in 100g water is 732mm. If kb=0.52 the boiling point of this solution will be
Given :WB=6.5 g,WA=100 g,ps=732 mm,Kb=0.52
Tb°=100°C,p°=760 mm
p°-psp°=n2n1⇒760-732760=n2100/18
⇒n2=28×100760×18=0.2046 moles
ΔTb=Kb×m
Tb-Tb°=Kb×n2×1000WA(g)
Tb-100°C=0.52×0.2046×1000100=1.06Tb=100+1.06=101.06°C