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Q.

Calcium imide on hydrolysis will give gas (B) which on oxidation by bleaching powder given gas (C). Gas (C) on reaction with magnesium gives compound (D). (D) on hydrolysis gives again gas (B). (B), (C) and (D) are:

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a

NH3 , N2, Mg3N2

b

N2, NH3, MgNH

c

N2, N2O5, Mg(NO3)2

d

NH3, NO2, Mg(NO2)2

answer is A.

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Detailed Solution

Ca(NH)+2H2O → Ca(OH)2+NH3(g) 2NH3+3CaOCl2 → N2(g)+3CaCl2+3H2ON2(g)+3Mg→Mg3N2Mg3N2+6H2O→3Mg(OH)2+2NH3Hence B=NH3 , C=N2 , D = Mg3N2

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