Calculate the entropy change when 3.6 g of liquid water is completely converted into vapour at 1000C. The molar heat of vaporization is 40.85 kJ mol-1.
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a
6.08 J K-1
b
109.5 J K-1
c
21.89 J K-1
d
-21.89 J K-1
answer is C.
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Detailed Solution
∆Hvap=40850 J mol-1, Tb=373 K ∆Svap= ∆HvapTb=40850 J mol-1373 K=109.5 K-1 mol-1 ∆Svap per gram = 109.5 J K-1 mol-118 g mol-1=6.083 J K-1 g-1 Entropy change for 3.6 g water = 6.083 J K-1 g-1 × 3.6 g = 21.89 J K-1