Calculate the equilibrium constant for the reaction, Zn(s)+Cu2+(aq)⟶Zn2+(aq)+Cu(s) Given, Ecell ∘=1.1V
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a
2×1032
b
2×1034
c
2×1037
d
2×1039
answer is C.
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Detailed Solution
Zn(s)+Cu2+(aq)⟶Zn2+(aq)+Cu(s)0=Ecell=Ecell∘−2.303RT2FlogZn2+Cu2+or Ecell∘=2.303RT2FlogZn2+Cu2+But at equilibrium Zn2+Cu2+=KC Ecell ∘=0.059V2logKC=1.1VlogKC=1.1V×20.059V=37.288 KC=2×1037 at 298K