Calculate the molar solubility (S) of a salt like zirconium phosphate of molecular formula Zr 3PO4 4
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a
Ksp96121/8
b
Ksp69121/7
c
Ksp53481/6
d
Ksp84351/7
answer is B.
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Detailed Solution
Consider a salt, zirconium phosphate of molecular formula Zr4+3PO43-4. It dissociates into 3 zirconium cations of charge +4 and 4 phosphate anions of charge -3.Zr4+=3S and PO43-=4Sand Ksp=(3S)3(4S)4=6912(S)7or S=Ksp/33×441/7=Ksp/6912I/7