Q.

Calculate the molar solubility (S) of a salt like zirconium phosphate of molecular formula Zr 3PO4 4

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a

Ksp96121/8

b

Ksp69121/7

c

Ksp53481/6

d

Ksp84351/7

answer is B.

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Detailed Solution

Consider a salt, zirconium phosphate of molecular formula Zr4+3PO43-4. It dissociates into 3 zirconium cations of charge +4 and 4 phosphate anions of charge -3.Zr4+=3S   and   PO43-=4Sand     Ksp=(3S)3(4S)4=6912(S)7or      S=Ksp/33×441/7=Ksp/6912I/7
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