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Q.

Calculate the O-H bond energy in the hydroxyl radical fromation the following data in kcalΔHf0 of OH(g)→+10.06kcalH2(g)→2H(g)-104.18kcalO2(g)→2O(g)-118.22kcal

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answer is 101.14.

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Detailed Solution

required equationO-H(g)→O(g)+H(g) ΔH=?12H2(g)+12O2(g)→OH(g) ΔH=+10.06kcalH2(g)→2H(g) ΔH=+104.18kcalO2(g)→2O(g) ΔH=+118.22kcal12×eq2+12×eq3-eq1ΔH=101.14kcal

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