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Calculate the pressure exerted by one mole of CO2 gas at 273 K if the van der Waals' constant a = 3.592 dm6 atm mol-2. Assume that the volume occupied by CO2 molecules is negligible.

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a

1 atm

b

2 atm

c

3 atm

d

4 atm

answer is A.

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Detailed Solution

In case of negligible morecular volume, b = 0 and van der Waals' equation reduces top+n2aV2V=nRT,p=RTV−aV2(n=1 mole ) =0.082×27322.4−3.592(22.4)2=0.99atm≈1atm

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Calculate the pressure exerted by one mole of CO2 gas at 273 K if the van der Waals' constant a = 3.592 dm6 atm mol-2. Assume that the volume occupied by CO2 molecules is negligible.