Calculate the resonance energy of nitrous oxide from the following data ΔHf0 of N2ON=N=O is 82 k J mol−1 ; N≡N: 946 k J mol−1 ;N=N: 418 k J mol−1 ; O=O: 498 k J mol−1 ;N=O: 607 k J mol−1
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Detailed Solution
N2O structure N = N = OGiven N2+12O2→N2O , ∆Hf0 =82 KJmol-1ΔHf0=N≡N+12O=O−1N=N-1N=O=946+12498−418+607=+170 kJResonance energy =ExP. ΔHf(N2O)−cal. ΔHf(N2O)=82−170=−88 k J mol−1