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Q.

Calculate the work done when 2 moles of hydrogen expand isothermally and reversibly at 270C from 15 to 50 litres

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a

14.45 kcal

b

1445 J

c

1445 cal

d

14.45 kJ

answer is C.

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Detailed Solution

W=-2.303 nRT log V2V1 =-2.303 × 2 × 2 × 300 log 5015 =-2763.6 log 10-log3 =-2763.6 1-0.4771 =-2763.6 × 0.5227 = -1445 cal
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