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Q.

Calomel is mercurous chloride which exist as a dimer. If its molar solubility in water is 10–2M, then its solubility product will be

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a

4 X 10-6

b

4 X 10-4

c

4 X 10 -8

d

8 X 10-6

answer is A.

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Detailed Solution

Hg2Cl2(s)⇌Hg2Cl2S(aq)→Hg2+2S(aq)+2Cl-2s(aq)Ksp=S×(2S)2=4S3=4×10-23Ksp=4×10-6
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