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Q.

A candle is burnt in a beaker until it extinguishes itself. A sample of gaseous mixture in the beaker contains6.08 x 1020 molecules of N2, 0.76 x 1020 molecules of O2, and 0.50 x 1020 molecules of CO2.The total pressure is734mm of Hg. The partial pressure of O2 would be

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a

760.0 mm of Hg

b

76.0 mm of Hg

c

7.6 mm of Hg

d

0.76 mm of Hg

answer is B.

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Detailed Solution

pO2=PTotal ×χO2 (mole fraction of O2χO2=nO2nO2+nN2+nCO2χO2=0.76×1020(0.76+0.50+6.08)×1020=0.767.34pO2=PTotal ×χO2=734×0.767.34=76.0mm of Hg
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