Q.

In the Cannizzaro reaction given below,2PhCHO →-OH PhCH2OH+PhCO2−, the slowest step is

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a

the attack of -OH at the carbonyl group,

b

the transfer of hydride to the carbonyl group,

c

the abstraction of proton from the carboxylic acid,

d

the deprotonation of PhCH2OH.

answer is B.

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Detailed Solution

The possible mechanism isThe slowest step is the transfer of hydride to the carbonyl group as shown in step (ii).
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