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Q.

For a Cannizzaro reaction,R−CHO+NaOH⟶Rate law is derived as: Rate =k[RCHO]2HO−2From the above rate law, it can be concluded that

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a

hydride donor is a dianion

b

reaction involves hydride ion transfer

c

reaction does not show kinetic isotopic effect

d

reaction is pseudo 2nd order

answer is A.

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Detailed Solution

For formation of dianion hydride donor, an additional mole of NaOH is consumed.Hence, rate becomes 2nd order with respect to HO– and fourth order overall.
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For a Cannizzaro reaction,R−CHO+NaOH⟶Rate law is derived as: Rate =k[RCHO]2HO−2From the above rate law, it can be concluded that