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In the carbon family, the elements other than carbon do not form pπ-pπ bonds because the atomic orbitals are:

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By Expert Faculty of Sri Chaitanya
a
Small and diffuse to undergo effective lateral overlap.
b
Large and diffuse to undergo effective Lateral overlap.
c
Large and far too less diffuse to overlap linearly.
d
small to overlap both laterally and linearly.
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detailed solution

Correct option is B

Heavier elements of group 14th do not form pπ-pπ bonds because their atomic orbital are too large and diffuse to have effective sideways overlapping.


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