Q.
CCl4 does not show hydrolysis but SiCl4 is readily hydrolysed because:
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a
IP of carbon is higher than that of silicon
b
electronegativity of carbon is higher than that of silicon
c
carbon cannot expand its octet but silicon can expand
d
carbon forms double and triple bonds but not silicon
answer is C.
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Detailed Solution
SiCl4 is readily hydrolyzed to produce Si(OH)2 where as CCl4 does not hydrolyzed due to lack of empty d-orbitals.
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