Q.

CCl4 does not show hydrolysis but SiCl4 is readily hydrolysed because:

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a

IP of carbon is higher than that of silicon

b

electronegativity of carbon is higher than that of silicon

c

carbon cannot expand its octet but silicon can expand

d

carbon forms double and triple bonds but not silicon

answer is C.

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Detailed Solution

SiCl4 is readily hydrolyzed to produce Si(OH)2 where as CCl4 does not hydrolyzed due to lack of empty d-orbitals.
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