The Cell has emf of 0.140V at 298K and 1 bar. Close to 298 K emf varies with temperature by 1.39 × . How much heat is absorbed by the cell if it discharges isothermally and reversibly to deposit one gram equivalent of copper from its aqueous solution in units of KJ? (1 F = 96479 C)
q =TDS = 298 × 13.41=4 KJ