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Q.

In a cell that utilizes the reaction, Zn(s)+2H(aq.)+→Zn(aq.)+2+H2(g), addition of H2SO4 to cathode compartment will:

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a

increase the E and shift equilibrium to the left

b

lower the E and shift equilibrium to the right

c

increase the E and shift equilibrium to the right

d

lower the E and shift equilibrium to the left

answer is C.

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Detailed Solution

Ecell=Ecello+0.0591log⁡[H+]2PH2×[Zn2+]Addition of H2SO4 will increase [H+] and thus Ecell will be more and equilibrium will shift to right.
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