Q.
A certain compound (X) when treated with copper sulphate solution yields a brown precipitate. On adding hypo solution the precipitate turns white. The compound is
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a
K2CrO3
b
KI
c
KBr
d
K3PO4
answer is B.
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Detailed Solution
KI reacts with CuSO4 solution to produce cuprous iodide (white precipitate) and I2 (which gives brown colour). Iodine reacts with hypo solution. Decolourisaiton of solution shows the appearance of white precipitate.CuSO4+2KI→CuI2+K2SO42CuI2→White ppt.2CuI+BrownI2 I2+2Na2S2O3→colourlessNa2S4O6+2NaI
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