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Q.

For a certain gas  Which deviates a little from ideal behavior A plot between p/ρ vs P was found to be non-linear, the intercept on y-axis will be

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a

RTM

b

MRT

c

MZRT

d

RTM

answer is A.

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Detailed Solution

P(V−nb)=nRTPV−Pnb=nRTPV=nRT+P⋅nbP⋅ Mass d=nRT+P⋅nbPd=n Mass ⋅RT+P⋅n⋅b Mass Pd=RTM+P⋅bM
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For a certain gas  Which deviates a little from ideal behavior A plot between p/ρ vs P was found to be non-linear, the intercept on y-axis will be