A certain quantity of Ammonium chloride is boiled with 100 ml of 0.8 N NaOH till no further action occurs. Excess of NaOH required 40 ml of 0.75 N sulphuricacid to neutralise if. How much Ammonium chloride was used?
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a
405 g
b
5 g
c
2.675 g
d
1 g
answer is C.
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Detailed Solution
V ml of 0.8 N NaOH ≅40 ml of 0.75N H2SO4V×0.8=40×0.75V=37.5 mlVolume of 0.8 N NaOH consumed by NH4Cl=100-37.5=62.5 mlnumber of moles of NaOH=0.05 therefore number of moles of NH4Cl will be 0.05 hence 53.5 x 0.05 = 2.675 grams