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Q.

A certain quantity of a gas occupies 100ml when collected over water at 15°C and 750mm pressure. If it occupies 91.9ml in dry state at STP, the vapour pressure of water at 15°C is

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a

12.8mm

b

14.8mm

c

13.2mm

d

17.3mm

answer is C.

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Detailed Solution

Let ' f ' is aqueous tensionAccording to Dalton's law Pdry gas = Pmoist gas - fP1V1T1=P2V2T2=(750-f)×100288=760×91.9273=255.839750 - f   =   736.81f = 13.2
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