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Q.

At certain temperature for the reaction NH4HS(S)⇌NH3(g)+H2S(g)  the equilibrium pressure found to be “P atm”  . Now  H2S(g) was added to it at same temperature until the partial pressure of H2S(g) at new equilibrium become “P atm”. The partial pressure of NH3 at new equilibrium is

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a

P4atm

b

2P atm

c

P2atm

d

P22atm

answer is A.

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Detailed Solution

For the given reaction =PNH3PH2S=P2atmP2atm=P24atm2As temperature remains the same, there is no change in equilibrium constant∴P24atm2=PNH3(Patm)Partial pressure of ammonia PNH3=P4 atm
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