At a certain temperature and total pressure of 105 Pa, Iodine vapour contains 40% by volume of I-atoms.I2(g) ⇌ 2I(g) Calculate Kp for the equilibrium,
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a
2.67×104 Pa
b
7.2×105 Pa
c
3.67×105 Pa
d
4.66×107 Pa
answer is A.
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Detailed Solution
Given, I-atoms in iodine vapour = 40% by volumeMole fraction of I atoms = 40100I2 Molecules inIodine vapours = 60% by volumeMole fraction of I2= 60100Partial pressure of I-atomsp1=40100×105=4×104 PaSimilarly, partial pressure of iodine molecules I2,p2=60100×105=6×104 PaKp=pI2pI2=[4×104] 2[6×104]=2.67×104 Pa