Q.

CH3a—CH2b—CH2c—CH2d—F Arrange the hydrogens a,b, c, d, in decreasing order of their reactivities towards chlorination

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a

b>c>d>a

b

b>c>a>d

c

a>b>c>d

d

c>b>a>d

answer is A.

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Detailed Solution

Selectivity of Cl is 3° > 2° > 1° H-atom. Due to -I effect of F, reactiviry of (d) is less and reactivity of b > c and c > a.
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CH3a—CH2b—CH2c—CH2d—F Arrange the hydrogens a,b, c, d, in decreasing order of their reactivities towards chlorination