Q.
CH3COOH(l) + C2H5OH(l) ⇋ CH3COOC2H5(l) + H2O(l) In the above reaction, one mole of each of acetic acid and alcohol are heated in the presence of little conc. H2SO4. On equilibrium being attained
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a
1 mole of ethyl acetate is formed
b
2 mole of ethyl acetate are formed
c
1.5moles of ethyl acetate is formed
d
2/3 moles of ethyl acetate is formed
answer is D.
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Detailed Solution
CH3COOH(l)+C2H5OH(l)⇌CH3COOC2H5(l)+H2O(l) Initially: 1mol 1mol 0 0 at Equil. : 1-x x x x where, x=degree of dissociation, It never be >1Hence In presence of little H2SO4 (as catalyst) about 2/3 mole of each of CH3COOH and C2H5OH react to form 2/3 mole of the product at equilibrium.
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