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Q.

(CH3)2SiCl2 undergoes hydrolysis but (CH3)2CCl2 does not. This is because

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a

d-orbitals are present in valence shell of Si but not in C

b

only 3p-orbital is involved in bonding in C

c

silicon is more acidic

d

Si-Cl bond is more polar than C - Cl bond

answer is A.

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Detailed Solution

Due to the presence of empty d-orbitals in the valence shell of 'Si'(CH3)2SiCl2 can accept the electron pair from water and undergoes hydrolysisExcited state configuration of 'Si'  is  [Ne] 3S1 3P3 3d0Where as in case of  (CH3)2CCl2 , the central atom carbon donot have empty d-orbitals in its valence shelland it is unable to accept the electron pair from water   Hence it can not undergo hydrolysis
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(CH3)2SiCl2 undergoes hydrolysis but (CH3)2CCl2 does not. This is because