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Q.

Choose the correct statement(s) among the following :

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a

[FeCl4]– has tetrahedral geometry.

b

[Co(en)(NH3)2Cl2]+ has 2 geometrical isomers

c

[FeCl4]– has higher spin-only magnetic moment than [Co(en)(NH3)2Cl2]+.

d

The cobalt ion in [Co(en)(NH3)2Cl2]+ has sp3 d2 hybridization.

answer is A.

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Detailed Solution

1) [FeCl4]- [FeCl4]- is sp3 hybridised and has tetrahedral geometry with 5 unpaired electrons2) [Co(en)(NH3)2Cl2]+ has three geometrical isomers.3) [FeCl4]- Number of unpaired electrons (n) = 5 Spin only magnetic moment  =n(n+2) B.M.                                                   =5.92B.M Co(en)NH32Cl2+Number of unpaired electrons (n) = 0 Spin only magnetic moment =n(n+2) B.M.                                               = 04) Co(en)NH32Cl2+[Co(en)(NH3)2Cl2]+ is d2 sp3 hybridised and has octahedral geometry with 0 unpaired electron
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