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answer is 3.
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Detailed Solution
ΔS has negative value if Δng=− ve i.e. number of gaseous moles decreasing during a reactionFor (a) Δng=2−0=2For(b) Δng=2−1=1For(c) Δng=2−3=−1For(d) Δng=3−0=3For (e) Δng=1−0=1