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Q.

Choose the Wrong statement amongst the following

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a

Chlorine water on long standing loses its yellow colour due to the formation of HCl and HOCl

b

The composition of bleaching power is Ca(OCl)2.CaCl2.Ca(OH)2.2H2O

c

The bleaching action of chlorine water is due to reduction

d

Chlorine gives addition products with low molecular weight unsaturated hydrocarbons.

answer is C.

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Detailed Solution

The bleaching action of chlorine water is due to oxidation.H2O + Cl2→ HCl + HOCl.Hypochlorous acid is unstable and decomposes to give nascent oxygen.Thus moist chlorine acts as oxidant and bleaching agent.HOCl →HCl + (O)
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