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Q.

Cl-CH2-CH2-CH2-CH2-Cl→hexane 1, 6-diamine. The proper sequence of reagents used to bring about the conversion is

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a

AgCN/C2H5OH; H3O+

b

NaCN/C2H5OH; H2/Ni

c

KCN/C2H5OH; H3O+

d

NH3/C2H5OH; aq KOH

answer is B.

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Detailed Solution

Cl-(CH2)4-Cl →C2H5OHNaCN or KCNNC-CH24-CN; NC-CH24-CN →or Na-Hg/C2H5OHH2/Catalyst or LiAlH4H2N-CH2-CH24-CH2-NH2;
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Cl-CH2-CH2-CH2-CH2-Cl→hexane 1, 6-diamine. The proper sequence of reagents used to bring about the conversion is